Issue 12, 2002
From the journal:

New Journal of Chemistry

Synthesis and structure of a one-dimensional cobalt(ii) coordination polymer with 1,3-bis(1,2,4-triazol-1-yl)propane

Qihua Zhao,ab   Haifang Li,b   Xiaofeng Wangb  and  Zhida Chen*ac  

* Corresponding authors

a State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, P. R. China
E-mail: zdchen@pku.edu.cn
Fax: +86 10 6275 1708
Tel: +86 10 6275 1016

b Department of Chemistry, Yunnan University, Kunming, P. R. China

c Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, P. R. China

Abstract

A novel 1D-coordination polymeric Co(II) complex [Co(btp)2(NCS)2]n [1, btp = 1,3-bis(1,2,4-triazol-1-yl)propane] was synthesized and characterized. The coordination geometry of the cobalt ions is distorted octahedral, with the equatorial plane formed by the four nitrogen atoms of the four triazole groups and the axial sites occupied by two terminal trans thiocyanato ligands. The Co(II) ions are linked by the btp ligands, building up coordination polymers of infinite 1D-neutral chains.

Graphical abstract: Synthesis and structure of a one-dimensional cobalt(ii) coordination polymer with 1,3-bis(1,2,4-triazol-1-yl)propane

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Article information

DOI
https://doi.org/10.1039/B206315H
Article type
Letter
Submitted
01 Jul 2002
Accepted
11 Sep 2002
First published
25 Oct 2002

New J. Chem., 2002,26, 1709-1710

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Synthesis and structure of a one-dimensional cobalt(II) coordination polymer with 1,3-bis(1,2,4-triazol-1-yl)propane

Q. Zhao, H. Li, X. Wang and Z. Chen, New J. Chem., 2002, 26, 1709 DOI: 10.1039/B206315H

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