Issue 9, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and characterization of a novel ring-like decamolybdate

Guang Liu,a   Shi-Wei Zhang*a  and  You-Qi Tanga  

* Corresponding authors

a State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
E-mail: zsw@chem.pku.edu.cn

Abstract

The reduction of heptamolybdate in acetic aqueous solution resulted in two polymorphic crystals with composition (NH4)2[Y(H2O)5]2·[MoVI6MoV4O30(CH3COO)4]·16H2O. This polyanion exhibited a novel ring-like decamolybdate structure. Two Y atoms were captured by the polyanion and covered the central hole of the ring. MoV–MoV bonds were also found in this mixed-valence compound.

Graphical abstract: Synthesis and characterization of a novel ring-like decamolybdate

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Article information

DOI
https://doi.org/10.1039/B108997H
Article type
Paper
Submitted
03 Oct 2001
Accepted
26 Feb 2002
First published
10 Apr 2002

J. Chem. Soc., Dalton Trans., 2002, 2036-2039

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Synthesis and characterization of a novel ring-like decamolybdate

G. Liu, S. Zhang and Y. Tang, J. Chem. Soc., Dalton Trans., 2002, 2036 DOI: 10.1039/B108997H

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