Issue 71, 2002

Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?

Abstract

Interconversion of chain co-ordination polymers {[Ag(4,4′-bipy)](X)} (X = NO3 or BF4) in aqueous media has been studied by IR and 1H NMR spectroscopy, transmission electron (TEM) and atomic force (AFM) microscopies and by X-ray powder diffraction (PXRD). The exchange leads to the formation of a pure crystalline phase of a new co-ordination polymer, and detailed TEM and AFM studies indicate a solvent-mediated rather than a solid-state mechanism for the exchange process.

Article information

Article type
Paper
Submitted
04 Mar 2002
Accepted
01 May 2002
First published
19 Jul 2002

CrystEngComm, 2002,4, 426-431

Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?

A. N. Khlobystov, N. R. Champness, C. J. Roberts, S. J.B. Tendler, C. Thompson and M. Schröder, CrystEngComm, 2002, 4, 426 DOI: 10.1039/B202217F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements