Issue 42, 2002
From the journal:

CrystEngComm

Building cyclotriveratrylene host molecules into network structures†

Ruksanna Ahmada  and  Michaele J. Hardie*a  

* Corresponding authors

a Department of Chemistry, University of Leeds, Leeds, UK
E-mail: m.j.hardie@chem.leeds.ac.uk

Abstract

Cyclotriveratrylene is a rigid bowl-shaped host molecule that can be used as a 3-connecting crystal engineering tecton by virtue of its tris-dimethoxy arrangement which may act as hydrogen bond acceptors, or chelating ligand sites. Network structures of unusual topology have resulted, and a number of common structural types are emerging. The tetragonal structure of [Fe(H2O)6]{(CH3CN)(CTV)}4(H2O)4[Co(C2B9H11)2]2 has been determined and features an unusual 3,12-connected 3D hydrogen bonded network structure, with the [Fe(H2O)6]2+ complex cation disordering to achieve the required geometry for the network. The structure of [Ag(CTV)2(H2O)3(CH3CN)2](CB11H12) has been determined and likewise conforms to a key structural type, and shows novel coordination of CTV to Ag+ centres.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B202197H
Article type
Paper
Submitted
04 Mar 2002
Accepted
05 Apr 2002
First published
15 Jul 2002

CrystEngComm, 2002,4, 227-231

Permissions

Request permissions

Building cyclotriveratrylene host molecules into network structures

R. Ahmad and M. J. Hardie, CrystEngComm, 2002, 4, 227 DOI: 10.1039/B202197H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements