This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Chemical Communications >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42.50*)
*Exclusive of taxes
This article contains 2 page(s)
Abstract | Cited by

Steric hindrance to solvation disfavors structures like 1syn-anti in which the melamine exposes to the solvent faces, such as tBu–H, for whom binding to the ring nitrogen is hindered but not blocked; steric hindrance to solvation lowers the barriers to rotation in solvents which bind the triazine nitrogens, therefore these solvents display the fastest rates for assembling/disassembling processes.

Graphical abstract: Steric hindrance to the solvation of melamines and consequences for non-covalent synthesis

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register