Issue 11, 2002
From the journal:

Chemical Communications

An unprecedented example of a cis-phosphonodithioato nickel(ii) complex built by an extensive hydrogen bonding supramolecular network

Vincenzo G. Albano,a   M. Carla Aragoni,b   Massimiliano Arca,b   Carlo Castellari,a   Francesco Demartin,c   Francesco A. Devillanova,b   Francesco Isaia,b   Vito Lippolis,b   Laura Loddob  and  Gaetano Verani*b  

* Corresponding authors

a Dipartimento di Chimica ″G. Ciamician″, Via Selmi 2, Bologna, Italy

b Dipartimento di Chimica Inorganica ed Analitica, Cittadella Universitaria, S.S. 554 bivio Sestu, Monserrato, CA, Italy
E-mail: verani@unica.it

c Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Via G. Venezian 21, Milano, Italy

Abstract

The P–N bond hydrolysis of the 4-methoxyphenyl-ammonium ethylamido-phosphonodithioato ligand during its complexation to NiII leads to the first example of phosphonodithioato nickel(II) complex having a cis configuration; this complex is stabilised in the solid state by an extensive and intricate network of hydrogen bondings involving the released ethylenediamine and a water molecule.

Graphical abstract: An unprecedented example of a cis-phosphonodithioato nickel(ii) complex built by an extensive hydrogen bonding supramolecular network

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B200414C
Article type
Communication
Submitted
11 Jan 2002
Accepted
14 Feb 2002
First published
02 May 2002

Chem. Commun., 2002, 1170-1171

Permissions

Request permissions

An unprecedented example of a cis-phosphonodithioato nickel(II) complex built by an extensive hydrogen bonding supramolecular network

V. G. Albano, M. C. Aragoni, M. Arca, C. Castellari, F. Demartin, F. A. Devillanova, F. Isaia, V. Lippolis, L. Loddo and G. Verani, Chem. Commun., 2002, 1170 DOI: 10.1039/B200414C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements