Issue 8, 2002

Continuous hydroamination in a liquid–liquid two-phase system

Abstract

The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid–liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF3SO3)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.

Graphical abstract: Continuous hydroamination in a liquid–liquid two-phase system

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2001
Accepted
08 Mar 2002
First published
26 Mar 2002

Chem. Commun., 2002, 906-907

Continuous hydroamination in a liquid–liquid two-phase system

V. Neff, T. E. Müller and J. A. Lercher, Chem. Commun., 2002, 906 DOI: 10.1039/B111630D

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