Issue 2, 2002
From the journal:

Chemical Communications

One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconocene†

Changjia Zhao,a   Tao Yua  and  Zhenfeng Xi*ab  

* Corresponding authors

a Department of Chemistry, Peking University, Beijing, China
E-mail: zfxi@pku.edu.cn

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China

Abstract

Zirconacyclopentenes generated in situ from alkynes and ethylene undergo selective reaction with aldehydes to afford homoallylketones in yields exceeding 70% in the presence of AlCl3.

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Article information

DOI
https://doi.org/10.1039/B109761J
Article type
Communication
Submitted
26 Oct 2001
Accepted
27 Nov 2001
First published
09 Jan 2002

Chem. Commun., 2002, 142-143

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One-pot synthetic route to homoallylketones via selective combination of alkyne, ethylene and aldehyde mediated by AlCl3 and zirconocene

C. Zhao, T. Yu and Z. Xi, Chem. Commun., 2002, 142 DOI: 10.1039/B109761J

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