Structure–reactivity correlations in the aminolysis of aryl dithiomethyl- and dithiophenylacetates with anilines in acetonitrile
Abstract
The kinetics and mechanism of the anilinolysis (XC6H4NH2) of dithio S)SC6H4Z with R = C2H5 and C6H5CH2 are investigated in
S) rather than
O)
S and σ*C–LG levels than those of the corresponding antibonding levels in the carbonyl esters. The normal kinetic isotope effects, kH/kD > 1.0, involving deuterated