Issue 2, 2001

Abstract

Electrode potential measurements for the title cell are presented from which thermodynamic parameters are obtained. The E[circle, cut, short horiz bar] values are lower than those of the same cell with pure electrolyte which results from an increase in the entropy term. There is also a decrease in the α–β transition temperature, which is ascribed to a decrease in the formation energy of the Frenkel defects which in turn is associated with the entropic change.

Article information

Article type
Paper
Submitted
09 Jun 2000
Accepted
07 Nov 2000
First published
05 Jan 2001

J. Mater. Chem., 2001,11, 628-629

Equilibrium potential, enthalpy and entropy values for the cell Ag/Ag0.94Cs0.06I/graphite, I2 (g)

M. E. Sola, R. S. Pettigrosso and J. C. Bazán, J. Mater. Chem., 2001, 11, 628 DOI: 10.1039/B004604N

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