Issue 9, 2001

A C3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

Abstract

A hexadentate podand ligand having C3 symmetry has been prepared, consisting of a tris(pyrazolyl)borate core bearing pinene-functionalised 2-pyridyl units attached to the C3 position of each pyrazolyl ring such that each arm is a chiral bidentate chelate; complexes with Tl(I) and Tb(III) have been prepared and structurally characterised.

Graphical abstract: A C3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
12 Mar 2001
Accepted
02 Apr 2001
First published
12 Apr 2001

J. Chem. Soc., Dalton Trans., 2001, 1389-1391

A C3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

G. R. Motson, O. Mamula, J. C. Jeffery, J. A. McCleverty, M. D. Ward and A. von Zelewsky, J. Chem. Soc., Dalton Trans., 2001, 1389 DOI: 10.1039/B102295B

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