Issue 21, 2001
From the journal:

Chemical Communications

Reversible trapping of acid and base vapours into an amphoteric crystalline material

Dario Braga,*a   Gianna Cojazzi,b   Dario Emiliani,a   Lucia Mainia  and  Fabrizia Grepioni*c  

* Corresponding authors

a Dipartimento di Chimica G. Ciamician, University of Bologna, Via Selmi 2, Bologna, Italy.
E-mail: dbraga@ciam.unibo.it

b Centro CNR per la Fisica delle Macromolecole, c/o Dipartimento di Chimica G. Ciamician, Via Selmi 2, Bologna, Italy

c Dipartimento di Chimica, University of Sassari, Via Vienna 2, Sassari, Italy.
E-mail: grepioni@ssmain.uniss.it

Abstract

Exposure of the solid zwitterion [CoIII(η5-C5H4CO2 H)(η5-C5H4CO2)] to hydrated vapours of volatile acids (HCl, CF3CO2H, HBF4) or bases (NH3, NMe3, NH2Me) quantitatively produces the corresponding salts; the heterogeneous reactions are fully reversible, as the acid or base molecules can be removed by thermal treatment, regenerating the starting material.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B106984E
Article type
Communication
Submitted
02 Aug 2001
Accepted
20 Sep 2001
First published
18 Oct 2001

Chem. Commun., 2001, 2272-2273

Permissions

Request permissions

Reversible trapping of acid and base vapours into an amphoteric crystalline material

D. Braga, G. Cojazzi, D. Emiliani, L. Maini and F. Grepioni, Chem. Commun., 2001, 2272 DOI: 10.1039/B106984E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements