Issue 24, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situNMR study

Andrei S. Batsanov,a   Matthew G. Davidson,†*b   Ignacio Fernández,c   Judith A. K. Howard,a   Fernando López-Ortiz‡c  and  Richard D. Price†b  

* Corresponding authors

a Department of Chemistry, Science Laboratories, South Road, Durham, UK

b Department of Chemistry, University of Bath, UK

c Área de Química Orgánica, La Cañada de San Urbano, Universidad de Almería, Almería, España

Abstract

An X-ray crystal structure reveals that the attempted deprotonation of cyclopropyl(triphenyl)phosphonium bromide with sodium amide affords a chiral N-phosphine substituted iminophosphorane via an unusual mechanism that has been investigated by multi-nuclear and variable temperature in situ NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/B005816P
Article type
Communication
Submitted
19 Jul 2000
Accepted
25 Oct 2000
First published
28 Nov 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 4237-4239

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One pot synthesis of a chiral N-phosphine substituted iminophosphorane: X-ray structure and in situ NMR study

A. S. Batsanov, M. G. Davidson, I. Fernández, J. A. K. Howard, F. López-Ortiz and R. D. Price, J. Chem. Soc., Perkin Trans. 1, 2000, 4237 DOI: 10.1039/B005816P

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