Issue 19, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Ambient-temperature syntheses of layered iron(III) phosphates in silica gels

Andrew R. Cowleya  and  Ann M. Chippindale*b  

* Corresponding authors

a Chemical Crystallography Laboratory, University of Oxford, 9 Parks Road, Oxford, UK

b Department of Chemistry, University of Reading, Whiteknights, Reading, UK

Abstract

Two layered iron(III) phosphates, [C5NH6][Fe(HPO4)2(H2O)2] and [C3N2H5][Fe(HPO4)2(H2O)2], have been prepared in silica-gel media at ambient temperature and pressure. Their structures have been determined by single-crystal X-ray diffraction. The compounds contain similar inorganic layers constructed from FeO6 octahedra and PO4 tetrahedra, but differ in their layer stacking patterns. The compounds are the first layered iron phosphates to be reported in which the Fe∶P ratio is 1∶2.

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Article information

DOI
https://doi.org/10.1039/B003618H
Article type
Paper
Submitted
05 May 2000
Accepted
02 Aug 2000
First published
08 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3425-3428

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Ambient-temperature syntheses of layered iron(III) phosphates in silica gels

A. R. Cowley and A. M. Chippindale, J. Chem. Soc., Dalton Trans., 2000, 3425 DOI: 10.1039/B003618H

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