Issue 10, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Variability of (ring centroid)–Ln–(ring centroid) angles in the mixed ligand C5Me5/C8H8 complexes (C5Me5)Ln(C8H8) and [(C5Me5)Yb(THF)](μ-η8∶η8-C8H8)[Yb(C5Me5)]

William J. Evans,*a   Matthew A. Johnston,a   Robert D. Clarka  and  Joseph W. Zillera  

* Corresponding authors

a Department of Chemistry, University of California, Irvine, USA

Abstract

The trivalent mixed ligand metallocene complexes (C5Me5)Ln(C8H8) have been structurally characterized for Ln = Sm, Dy, Er, and Yb and compared with the known lutetium analog to study the effect of radial size and f n electron configuration on the (C5Me5 ring centroid)–Ln–(C8H8 ring centroid) angles. Analogous angles were also examined in the mixed ligand, bimetallic, partially-solvated complex [(C5Me5)Yb(THF)](μ-η8∶η8-C8H8)[Yb(C5Me5)].

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Article information

DOI
https://doi.org/10.1039/A908412F
Article type
Paper
Submitted
21 Oct 1999
Accepted
15 Mar 2000
First published
25 Apr 2000

J. Chem. Soc., Dalton Trans., 2000, 1609-1612

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Variability of (ring centroid)–Ln–(ring centroid) angles in the mixed ligand C5Me5/C8H8 complexes (C5Me5)Ln(C8H8) and [(C5Me5)Yb(THF)](μ-η8∶η8-C8H8)[Yb(C5Me5)]

W. J. Evans, M. A. Johnston, R. D. Clark and J. W. Ziller, J. Chem. Soc., Dalton Trans., 2000, 1609 DOI: 10.1039/A908412F

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