Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50–87%) epoxidation of alkenes under fluorous biphasic conditions.
Second-generation fluorous chiral (salen) manganese complexes
M. Cavazzini, A. Manfredi, F. Montanari, S. Quici and G. Pozzi, Chem. Commun., 2000, 2171 DOI: 10.1039/B007053J
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