Issue 18, 2000
From the journal:

Chemical Communications

Molecular architecture via coordination: quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group

Hajime Suzuki,a   Nobuo Tajima,b   Kazuyuki Tatsumib  and  Yasuhiro Yamamoto*a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Toho University, Miyama, Funabashi, Chiba, Japan.
E-mail: yamamoto@chem.sci.toho-u.ac.jp

b Research Center for Materials Science and Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chkusa-ku, Nagoya, Japan.
E-mail: i45100a@nucc.cc.nagoya-u.ac.jp

Abstract

Reactions of [Cp*MCl2]2 (M = Rh, Ir) with bidentate ligand (L = pyrazine; L′ = diisocyanide) gave [Cp*MCl2(L or L′}]2, which were converted into tetranuclear complexes [Cp*2M2Cl2(L)(L′)]2 (OTf)4 containing different ligands on treatment with Ag(OTf).

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Article information

DOI
https://doi.org/10.1039/B003416I
Article type
Communication
Submitted
27 Apr 2000
Accepted
09 Aug 2000
First published
06 Sep 2000

Chem. Commun., 2000, 1801-1802

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Molecular architecture via coordination: quasi-octahedral macrocycles of rhodium and iridium bearing a pentamethylcyclopentadienyl group

H. Suzuki, N. Tajima, K. Tatsumi and Y. Yamamoto, Chem. Commun., 2000, 1801 DOI: 10.1039/B003416I

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