The unexpected head-to-head dimerisation of 1H-phosphirenes
Abstract
Both 1H-phosphirenes and their P-W(CO)5 complexes readily dimerise in the presence of Ni(II) or Pd(0) catalysts to give the corresponding 1,2-dihydro-1,2-diphosphinines.
a
Laboratoire “Hétéroéléments et
Coordination”, UMR CNRS 7653, DCPH, Ecole Polytechnique, Palaiseau Cedex, France.
E-mail:
dcph@poly.polytechnique.fr
Both 1H-phosphirenes and their P-W(CO)5 complexes readily dimerise in the presence of Ni(II) or Pd(0) catalysts to give the corresponding 1,2-dihydro-1,2-diphosphinines.
The unexpected head-to-head dimerisation of 1H-phosphirenes
N. H. T. Huy, L. Ricard and F. Mathey, Chem. Commun., 2000, 1137 DOI: 10.1039/B001304H
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