Issue 3, 1999

Self-assembly of zinc aminoporphyrins

Abstract

The aniline–zinc porphyrin interaction is an order of magnitude weaker than the corresponding pyridine–zinc porphyrin interaction, but it is still strong enough to cause self-assembly of zinc aminoporphyrins in solution. Three isomeric systems are reported, two form self-assembled dimers, but the geometry of the third forces it to form an open chain oligomer. The stabilities and structures of the complexes have been determined using 1H NMR spectroscopy.

Article information

Article type
Paper

New J. Chem., 1999,23, 309-316

Self-assembly of zinc aminoporphyrins

M. Gardner, A. J. Guerin, C. A. Hunter, U. Michelsen and C. Rotger, New J. Chem., 1999, 23, 309 DOI: 10.1039/A807876I

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