Barium complex with 2,2,6,6-tetramethylheptane-3,5-dione and 4,7-diphenyl-1,10-phenanthroline
Abstract
The interaction between [Ba(dpm)]4 and anhydrous B-phen (mole ratio 1: 2) in benzene leads to the formation of the new mixed-ligand complex Ba(dpm)2(B-phen)27middot;C6H6, which consists of the mononuclear molecules Ba(dpm)2(B-phen)2 with the cis arrangement of B-phen ligands involved in both intermolecular and intramolecular π-π interactions.