Synthesis and characterization of electrically conducting polyaniline in water–oil microemulsion

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Feng Yan and Gi Xue


Abstract

Nanoscopic polyaniline particles were successfully synthesized in a stable water–oil microemulsion. FT-IR spectra showed that sodium dodecylbenzenesulfonate (SDBA) acted both as surfactant and dopant in the acidic reaction media. Wide-angle X-ray diffraction, UV–visible spectra and thermal analysis suggested that the crystallinity of PANI synthesized in the microemulsion system was increased dramatically while the chain-transfer reactions of co-surfactants decreased the π-conjugation length along the polymer chain.


References

  1. E. M. Genies, P. Hany and C. Santier, Synth. Met., 1989, 28, 647 CrossRef.
  2. N. S. Sariciftci and H. Kuzmany, J. Chem. Phys., 1990, 92, 4530 CrossRef CAS.
  3. A. F. Diaz and J. A. Logan, J. Electroanal. Chem., 1980, 111, 111 CrossRef CAS.
  4. M. Angelopoulos, G. E. Asturias, S. P. Ermer, A. Ray, E. M. Scherr and A. G. MacDiarmid, Mol. Cryst. Liq. Cryst., 1988, 160, 151.
  5. S. Wang, F. Wang and X. Ge, Synth. Met., 1986, 78, 1.
  6. S. A. Chen and H. T. Lee, Macromolecules, 1993, 26, 3254 CrossRef CAS.
  7. K. Shannon and J. Fernandez, J. Chem. Soc., Chem. Commun., 1994, 643 RSC.
  8. H. S. O. Chan, S. C. Ng, W. S. Sim, K. L. Tan and B. T. G. Tan, Macromolecules, 1992, 25, 6029 CrossRef CAS.
  9. S. Jin and G. Xue, Macromolecules, 1997, 30, 5753 CrossRef CAS.
  10. K. Ishizu, H. Tanaka and R. Saito, Polymer, 1996, 37, 863 CrossRef CAS.
  11. R. H. Ottewill and J. N. Shaw, J. Electroanal. Chem., 1972, 37, 133 CrossRef CAS.
  12. S. P. Armes and B. Vincent, J. Chem. Soc., Chem. Commun., 1987, 288 RSC; S. P. Armes and M. Aldissi, J. Chem. Soc., Chem. Commun., 1989, 88 RSC; N. Cawdery, T. M. Obey and B. Vincent, J. Chem. Soc., Chem. Commun., 1988, 1198 RSC.
  13. B. Vincent and J. Waterson, J. Chem. Soc., Chem. Commun., 1990, 683 RSC.
  14. N. Gospodinova, P. Mokreva, T. Tsanov and L. Terlemezyan, Polymer, 1997, 38, 43 CrossRef.
  15. J. Barton, Prog. Polym. Sci., 1996, 21, 399 CrossRef CAS.
  16. M. Antonietti, S. Lohmman and C. Vanniel, Macromolecules, 1989, 25, 1515.
  17. M. Dreja, W. Pyckhout-Hintzen and B. Tieke, Macromolecules, 1998, 31, 272 CrossRef CAS.
  18. F. Yan, C. Zheng, X. Zhai and D. Zhao, J. Appl. Polym. Sci., 1998, 67, 747 CrossRef CAS.
  19. S. Roy and S. Devi, J. Appl. Polym. Sci., 1996, 67, 1509 CrossRef.
  20. H. S. O. Chan, L. Ming, C. H. Chew and L. Ma, J. Mater. Chem., 1993, 3, 1109 RSC.
  21. D. Ichinohe, T. Arai and H. Kise, Synth. Met., 1997, 84, 75 CrossRef CAS.
  22. M. T. Nguyen and A. F. Diaz, Macromolecules, 1995, 28, 3411 CrossRef CAS.
  23. G. E. Asturias, A. G. MacDiarmid, R. P. McCall and A. J. Epstein, Synth. Met., 1989, 29, 157 CrossRef.
  24. R. Singh, V. Arora, R. P. Tandon and S. Chandre, Polymer, 1997, 38, 4897 CrossRef CAS.
  25. I. Kulszewicz-Bajer, J. Sobczak, M. Hasik and J. Pretula, Polymer, 1996, 37, 25 CrossRef CAS.
  26. L. F. Warren, J. A. Walker, D. P. Anderson, C. G. Rhodes and L. J. Buckley, J. Electroanal. Chem., 1989, 136, 2286 CAS.
  27. Y. Wei, G. W. Jang, K. F. Hsueh, E. M. Scherr, A. G. MacDiarmid and A. J. Epstein, Polymer, 1992, 33, 314 CAS.
  28. (a) F. Wang, J. Tang, W. L. Zhang and Z. Mo, Mol. Cryst. Liq. Cryst., 1988, 160, 175; (b) J.-E. Österholm, Y. Cao, F. Klavetter and P. Smith, Polymer, 1994, 35, 2902 CrossRef CAS.
  29. J. M. Ko, S. Kim and I. J. Chung, Synth. Met., 1995, 69, 139 CrossRef CAS.
  30. L. T. Cai, S. B. Yao and S. M. Zhou, Synth. Met., 1997, 88, 209 CrossRef CAS.
  31. A. G. MacDiarmid and A. J. Epstein, Synth. Met., 1996, 78, 1 CrossRef.
  32. D. S. Pearson, P. A. Pincus and G. W. Heffner, Macromolecules, 1993, 26, 1570 CrossRef CAS.
  33. W. Zheng, M. Angelopoulos, A. J. Epstein and A. G. MacDiarmid, Macromolecules, 1997, 30, 7634 CrossRef CAS.
  34. A. G. MacDiarmid and A. J. Epstein, Synth. Met., 1995, 69, 179 CrossRef CAS.
  35. M. E. Jozefowicz, R. Laversanne, H. H. S. Javadi, A. J. Epstein, J. P. Pouget, X. Tang and A. G. MacDiarmid, Phys. Rev. B, 1989, 39, 12 958 CrossRef CAS.
  36. W. B. Euler, Solid State Commun., 1986, 57, 857 CrossRef CAS; S. Stafstrom, J. L. Bredas, A. J. Epstein, H. S. Woo, D. B. Tanner, W. S. Huang and A. G. MacDiarmid, Phys. Rev. Lett., 1987, 59, 1464 CrossRef CAS.
  37. L. M. Gan, C. H. Chew, I. Lye, L. Ma and G. Li, Polymer, 1993, 34, 3860 CAS.
  38. X. Zeng and T. Ko, Polymer, 1998, 39, 1187 CrossRef CAS.
  39. B. C. Roy, M. D. Gupta and J. K. Ray, Macromolecules, 1995, 28, 1727 CrossRef CAS.
  40. S. Wang, F. Wang and X. Ge, Synth. Met., 1986, 16, 99 CAS.
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