Synthesis and spectroscopic characterisation of Y-doped Cd2SnO4

(Note: The full text of this document is currently only available in the PDF Version )

Antonino Gulino and Ignazio Fragalà


Abstract

Y-Doped cadmium oxide has been prepared by a solid state reaction of CdO and Y2O3 in air, and by a coprecipitation procedure starting from CdO and Y(NO3)3·6H2O. Y-Doped dicadmium stannate has been synthesised by firing well blended mixtures of Y-doped CdO and SnO2 in air. Both Y-doped CdO and Cd2SnO4, have been characterised by XRD, IR, EPR and XPS. XRD measurements confirm the presence of single cubic CdO and orthorhombic Cd2SnO4 phases. EPR analysis suggests an increased concentration of conduction electrons and electron mobility upon 2% Y-doping. IR specular reflectance spectra show enhanced reflectivity in the mid IR for Y-doped Cd2SnO4 samples. XPS measurements highlight yttrium segregation to the sample surface.


References

  1. W. Xiaochun, W. Rongyao, Z. Bingsuo, W. Li, L. Shaomei, X. Jiren and H. Wei, J. Mater. Res., 1998, 13, 604.
  2. X. Wu, T. J. Couts and W. P. Mulligan, J. Vac. Sci. Technol. A, 1997, 15, 1057 CrossRef CAS.
  3. T. J. Couts, X. Wu, W. P. Mulligan and J. M. Webb, J. Electron. Mater., 1996, 25, 935 Search PubMed.
  4. R. Dragon, S. Wacke and T. Gorecki, J. Appl. Electrochem., 1995, 25, 699 CAS.
  5. K. J. D. MacKenzie, C. M. Cardile and R. H. Meinhold, J. Phys. Chem. Solids, 1991, 52, 969 CrossRef CAS and references therein.
  6. T. Hashemi, C. H. Hogarth and F. Golestani-Fard, J. Mater. Sci., 1988, 23, 2645 CAS.
  7. C. M. Cardile, R. H. Meinhold and K. J. D. MacKenzie, J. Phys. Chem. Solids, 1987, 48, 881 CrossRef CAS.
  8. C. M. Lambert, Sol. Energy Mater., 1981, 6, 1 Search PubMed.
  9. D. E. Hall, J. Electrochem. Soc., 1980, 127, 308 CAS.
  10. F. P. Koffyberg and F. A. Benko, Appl. Phys. Lett., 1980, 37, 320 CrossRef CAS.
  11. N. Miyata, K. Miyake, K. Koga and T. Fukushima, J. Electrochem. Soc.: Solid-State Sci. Technol., 1980, 127, 918 Search PubMed.
  12. K. J. D. MacKenzie, W. A. Gerrard and F. Golestani-Fard, J. Mater. Sci. Lett., 1979, 14, 2509 CAS.
  13. K. J. D. MacKenzie, W. A. Gerrard and F. Golestani-Fard, Silic. Ind., 1979, 4–5, 97 Search PubMed.
  14. G. Haacke, W. E. Mealmaker and L. A. Siegel, Thin Solid Films, 1978, 55, 67 CrossRef CAS.
  15. G. Haacke, H. Ando and W. E. Mealmaker, J. Electrochem. Soc.: Solid-State Sci. Technol., 1977, 124, 1923 Search PubMed.
  16. A. J. Nozik, Phys. Rev. B, 1972, 6, 453 CrossRef CAS.
  17. Y. Dou, R. G. Egdell, T. Walker, D. S. L. Law and G. Beamson, Surf. Sci., 1998, 398, 241 CrossRef CAS.
  18. Y. Dou and R. G. Egdell, Surf. Sci., 1997, 372, 289 CrossRef CAS.
  19. Y. Dou and R. G. Egdell, Surf. Sci., 1997, 377–379, 181 CrossRef CAS.
  20. Y. Dou and R. G. Egdell, J. Mater. Chem., 1996, 6, 1369 RSC.
  21. F. P. Koffyberg, Solid State Commun., 1971, 9, 2187 CrossRef CAS.
  22. R. Haul and D. Just, J. Appl. Phys., 1962, 33, 487 CAS.
  23. A. Cimino and M. Marezio, J. Phys. Chem. Solids, 1960, 17, 57 CrossRef CAS.
  24. C. M. Cardile, Rev. Solid. State Sci., 1991, 5, 31 Search PubMed.
  25. R. Pis Diez, E. J. Baran, A. E. Lavat and M. C. Grasselli, J. Phys. Chem. Solids, 1995, 56, 135 CrossRef.
  26. M. S. Setty, J. Mater. Sci. Lett., 1987, 6, 909 CAS.
  27. F. Golestani-Fard, C. A. Hogarth and D. N. Waters, J. Mater. Sci. Lett., 1983, 2, 505 CAS.
  28. R. H. Meinhold, J. Phys. Chem. Solids, 1987, 48, 927 CrossRef CAS.
  29. R. G. Egdell, A. Gulino, C. Rayden, G. Peacock and P. A. Cox, J. Mater. Chem., 1995, 5, 499 RSC.
  30. A. Gulino, S. La Delfa, I. Fragalà and R. Egdell, Chem. Mater., 1996, 8, 1287 CrossRef CAS.
  31. R. P. Bonomo, E. Conte, G. De Guidi, G. Maccarrone, E. Rizzarelli and G. Vecchio, J. Chem. Soc., Dalton Trans., 1996, 4351 RSC.
  32. American Society for Testing and Material, Powder Diffraction Files, Joint Committee on Powder Diffraction Standards, USA, Set 1–5 Revised, Inorganic, 1974.
  33. M. Von Tromel, Z. Anorg. Allg. Chem., 1969, 371, 237 CrossRef CAS.
  34. R. D. Shannon, J. L. Gillson and R. J. Bouchard, J. Phys. Chem. Solids, 1977, 38, 877 CrossRef CAS.
  35. B. E. Warren, X-Ray Diffraction, Addison-Wesley, Reading, MA, 1969 Search PubMed.
  36. A. Gulino, A. E. Taverner, S. Warren, P. Harris and R. G. Egdell, Surf. Sci., 1994, 315, 351 CrossRef CAS and references therein.
  37. D. Majumdar and D. Chatterjee, J. Appl. Phys., 1991, 70, 988 CrossRef CAS.
  38. A. E. Hughes, J. Am. Ceram. Soc., 1995, 78, 369 CAS.
  39. D. Briggs and M. P. Seah, Practical Surface Analysis, Wiley, Chichester, 1994, 2nd edn Search PubMed.
  40. R. G. Egdell and S. C. Parker, in Science of Ceramic Interfaces, ed. J. Nowotny, Material Science Monographs no. 75, Elsevier, Amsterdam, 1991, p. 41, and references therein Search PubMed.
  41. W. C. Mackrodt and P. W. Tasker, J. Am. Ceram. Soc., 1989, 72, 1576 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.