Strong negative thermal expansion in the siliceous zeolites ITQ-1, ITQ-3 and SSZ-23

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David A. Woodcock, Philip Lightfoot, Paul A. Wright, Luis A. Villaescusa and Miguel A. Camblor


Abstract

Strong negative thermal expansion has been found for the pure SiO2 zzeolites ITQ-1 (αv=–12.1×10–6 K–1), SSZ-23 (αv=–10.3×10–6 K–1) and ITQ-3 (αv=–11.4×10–6 K–1) from 50 to 500[thin space (1/6-em)]°C and above.


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