Conducting charge-transfer and radical ion salts based on bitetrathiafulvalenes; an approach to organic metals using stoichiometry control

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Masahiko Iyoda, Eiji Ogura, Kenji Hara, Yoshiyuki Kuwatani, Hiroyuki Nishikawa, Tatsuo Sato, Koichi Kikuchi, Isao Ikemoto and Takehiko Mori


Abstract

Charge-transfer and radical ion salts of 4,5,4′″,5′″-tetramethylthio-, 4,5,4′″,5′″-bis(ethylenedithio)-, and 4,5,4″′,5″′-bis(ethylenedioxy)-4′,4″-bitetrathiafulvalenes showed fairly high electric conductivities, reflecting the effect of stoichiometry control.


References

  1. F. Wudl, G. M. Smith and E. J. Hufnagel, Chem. Commun., 1970, 1453 RSC; F. Wudl, D. Wobshall and E. J. Hufnagel, J. Am. Chem. Soc., 1972, 94, 670 CrossRef CAS; J. Ferraris, D. O. Cowan, V. Walatka, Jr. and J. H. Rerlstein, J. Am. Chem. Soc., 1973, 95, 948 CrossRef CAS.
  2. For general reviews, see: D. J. Sandman and G. P. Ceasar, Isr. J. Chem., 1986, 27, 293 Search PubMed; M. R. Bryce, Aldrichim. Acta, 1985, 18, 73 CAS; M. R. Bryce and L. C. Murphy, Nature, 1984, 309, 119 Search PubMed; J. H. Perlstein, Angew. Chem., Int. Ed. Engl., 1977, 16, 519 CrossRef CAS.
  3. For general reviews, see: M. R. Bryce, J. Mater. Chem., 1995, 5, 1481 Search PubMed; T. Otsubo, Y. Aso and K. Takimiya, Adv. Mater., 1996, 8, 203 RSC; M. Adam and K. Müllen, Adv. Mater., 1994, 6, 439 CAS; M. R. Bryce, Chem. Soc. Rev., 1991, 20, 355 CrossRef.
  4. K. Bechgaard, K. Lerstrup, M. Jørgensen, I. Johannsen and J. Christensen, The Physics and Chemistry of Organic Superconductors, ed. G. Saito and S. Kagoshima, Springer-Verlag, Berlin, 1990, p. 349 Search PubMed.
  5. M. Iyoda, Y. Kuwatani, N. Ueno and M. Oda, J. Chem. Soc., Chem. Commun., 1992, 153 RSC.
  6. For the synthesis of bitetrathiafulvalenes, see: (a) H. Tatemitsu, E. Nishikawa, Y. Sakata and S. Misumi, Synth. Met., 1987, 19, 565 CrossRef CAS; (b) J. Y. Becker, J. Bernstein, A. Ellern, H. Gershtenman and V. Khodorkovsky, J. Mater. Chem., 1995, 5, 1557 RSC; (c) D. E. John, A. J. Moore, M. R. Bryce, A. S. Batsanov and J. A. K. Howard, Synthesis, 1998, 826 CrossRef CAS.
  7. T. Mori and H. Inokuchi, Solid State Commun., 1987, 62, 525 CrossRef CAS.
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