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DOI: 10.1039/A807595F (Paper) Reference Section for: J. Mater. Chem., 1999, 9, 1237-1244

Structural, magnetic, electrical and optical characterization of systems built from [M([9]aneN3)2]2+ (M=CuII or NiII) and TCNQ or TCNQF4

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M. Teresa Azcondo, Loreto Ballester, Stephane Golhen, Angel Gutierrez, Lahcene Ouahab, Slav Yartsev and Pierre Delhaes

Abstract

Three different supramolecular architectures corresponding to [M([9]aneN3)2](TCNQ)2, (M=NiII1 or CuII2, [9]aneN3=1,4,7-triazacyclononane, TCNQ=7,7,8,8-tetracyanoquinodimethane), [Cu([9]aneN3)2](TCNQ)33 and [Cu([9]aneN3)2](TCNQF4)2, 4 (TCNQF4=2,3,5,6-tetrafluoro-7,7,8,8,-tetracyanoquinodimethane), have been prepared and crystallographically characterized: 1, triclinic, P1, a=8.6488(9), b=8.919(3), c=11.316(2) Å, α=82.06(2), β=74.331(10), γ=85.71(2)°, Z=1; 2, triclinic, P1, a=8.6806(11), b=8.915(5), c=11.348(2) Å, α=82.03(3), β=74.109(14), γ=84.95(2)°, Z=1; 3, triclinic, P1, a=8.350(2), b=9.884(4), c=14.369(4) Å, α=74.10(2), β=89.01(2), γ=69.11(2)°, Z=1; 4, triclinic, P1, a=15.476(5), b=16.146(4), c=16.441(4) Å, α=77.15(2), β=78.04(3), γ=85.43(3)°, Z=2. Compounds 1 and 2 are formed by dimeric (TCNQ)22– units and 4 by three different dimeric (TCNQF4)22– units. Compound 3 is formed by isolated [Cu([9]aneN3)2]2+ groups and trimeric (TCNQ)32– units. The electrical, optical and magnetic properties of the four new compounds have been interpreted on the basis of their supramolecular architectures.

References

  1. M. Kurmoo, A. W. Graham, P. Day, S. J. Coles, M. B. Hursthouse, J. L. Caulfield, J. Singleton, F. L. Pratt, W. Hayes, L. Ducasse and P. Guionneau, J. Am. Chem. Soc., 1995, 117, 12209 CrossRef CAS.
  2. W. Kaim and M. Moscherosch, Coord. Chem. Rev., 1994, 129, 157 CrossRef CAS; H. Zhao, R. A. Heintz, K. R. Dunbar and R. D. Rogers, J. Am. Chem. Soc., 1996, 118, 12844 CrossRef CAS.
  3. M. C. Grossel, Chem. Mater., 1996, 8, 977 CrossRef CAS; L. J. Pace, A. Ulman and J. A. Ibers, Inorg. Chem., 1982, 21, 199 CrossRef CAS.
  4. H. Endres, in Extended Linear Chain Compounds, ed. J. S. Miller, Plenum, New York, 1982, ch. 3, p. 263 Search PubMed; L. Ballester, A. Gutiérrez, M. F. Perpiñán, U. Amador, M. T. Azcondo, A. E. Sánchez-Peláez and C. Bellitto, Inorg. Chem., 1997, 36, 639 Search PubMed.
  5. L. Ballester, M. C. Barral, A. Gutiérrez, R. Jiménez-Aparicio, J. M. Martínez-Muyo, M. F. Perpiñán, M. A. Monge and C. Ruiz-Valero, J. Chem. Soc., Chem. Commun., 1991, 1396 RSC.
  6. L. Ballester, A. Gutiérrez, M. F. Perpiñán, M. T. Azcondo, A. E. Sánchez-Peláez and U. Amador, Anal. Quim. Int. Ed., 1996, 92, 275 Search PubMed.
  7. L. Ballester, A. M. Gil, A. Gutiérrez, M. F. Perpiñán, M. T. Azcondo, A. E. Sánchez-Peláez, U. Amador, J. Campo and F. Palacio, Inorg. Chem., 1997, 36, 5291 CrossRef CAS.
  8. X. Wang, L. M. Liable-Sands, J. L. Manson, A. L. Rheingold and J. S. Miller, Chem. Commun., 1996, 1979 RSC.
  9. L. R. Melby, R. J. Herder, W. Mahler, R. E. Benson and W. E. Mochel, J. Am. Chem. Soc., 1962, 84, 3374 CrossRef CAS.
  10. R. Yang and L. J. Zompa, Inorg. Chem., 1976, 15, 1499 CrossRef CAS.
  11. M. G. Nardelli, G. V. Gasparri, A. Musatti and A. Manfredotti, Acta Crystallogr., 1966, 21, 910 CrossRef CAS.
  12. P. Chaudhuri, K. Oder, K. Wieghardt, J. Weiss, J. Reedijk, W. Hinrichs, J. Wood, A. Ozarowsky, H. Stratemaier and D. Reinen, Inorg. Chem., 1986, 25, 2951 CrossRef CAS.
  13. S. Flandrois and D. Chasseau, Acta Crystallogr., Sect. B, 1977, 33, 2744 CrossRef.
  14. R. Bozio, A. Girlando and C. Pecile, J. Chem. Soc., Faraday Trans., 1975, 71, 1237 Search PubMed.
  15. R. Bozio, I. Zanon, A. Girlando and C. Pecile, J. Chem. Soc., Faraday Trans., 1978, 74, 235 Search PubMed.
  16. J. Ramos, V. M. Yartsev, S. Golhen, L. Ouahab and P. Delhaes, J. Mater. Chem., 1997, 7, 1313 RSC.
  17. M. Meneghetti, A. Girlando and C. Pecile, J. Chem. Phys., 1985, 83, 3134 CrossRef CAS.
  18. J. B. Torrance, Acc. Chem. Res., 1979, 12, 79 CrossRef CAS.
  19. M. Schwartz and W. E. Hatfield, Inorg. Chem., 1987, 26, 2823 CrossRef CAS.
  20. A. R. Amudsen, J. Whelon and B. Bosnich, J. Am. Chem. Soc., 1977, 99, 6730 CrossRef CAS.
  21. A. B. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1984, p. 356 Search PubMed.
  22. Y. Iida, Bull. Chem. Soc. Jpn., 1969, 42, 673.
  23. V. M. Yartsev, Phys. Status Solidi B, 1982, 112, 279 CAS.
  24. M. Futamata, Y. Morioka and I. Nakagawa, Spectrochim. Acta, Part A, 1983, 39, 515 CrossRef.
  25. M. J. Rice, V. M. Yartsev and C. S. Jacobsen, Phys. Rev. B, 1980, 21, 3437 CrossRef CAS.
  26. R. L. Carlin, Magnetochemistry, Springer-Verlag, Berlin, Heidelberg, 1986, p. 24 Search PubMed.
  27. B. Bleaney and K. D. Bowers, Proc. R. Soc. London, Ser. A, 1952, 214, 451 Search PubMed.
  28. J. Krzystek and J. U. Von Schutz, Adv. Chem. Phys., 1992, 86, 167.
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