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DOI: 10.1039/A805662E (Paper) Reference Section for: J. Mater. Chem., 1999, 9, 101-105

On the synthesis of monovalent, divalent and trivalent element vanadates

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Emmanuel Baudrin, Sophie Denis, François Orsini, Laurent Seguin, Marcel Touboul and Jean-Marie Tarascon

Abstract

A chimie douce method has been used to prepare vanadates (V5+) of various elements, trivalent (Al, Cr, Fe, In, Y, Bi), divalent (Co, Ni), monovalent (Li, Tl), and a combination of nickel and lithium. By varying several parameters, especially the pH during the synthesis, several types of vanadates have been obtained ranging from orthovanadates (VO43–) to decavanadates (V10O286–). The pH conditions required to prepare the various vanadates fall nicely within the expectations of the previously reported cation charge-pH diagram.

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