A Mixed-metal Mixed-halide Complex Prepared from Zerovalent Copper and Lead Salts: Solution and Solid-state Chemistry

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Larisa A. Kovbasyuk, Olga Yu. Vassilyeva, Vladimir N. Kokozay, Wolfgang Linert and Paul R. Raithby


Abstract

The mixed-metal mixed-halide complex [CuPbBrIL2]2 has been prepared by the direct interaction of zerovalent copper with lead halides and 2-dimethylaminoethanol (HL) in dmso and has been characterized by X-ray crystallography; the structure shows a layer arrangement of the tetranuclear metal units through the µ3-halogen bridging.


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