DOI: 10.1039/A904712C
(Paper)
Reference Section for: J. Chem. Res. (S), 1999, 658-659
Preparation of (±)-[1,2-13C2]Abscisic Acid for Use as a Stable and Pure Internal Standard
(Note: The full text of this document is currently only available in the PDF Version )
Tadao Asami, Katsuhiko Sekimata, Jing Ming Wang, Koichi Yoneyama, Yasutomo Takeuchi and Shigeo Yoshida
Abstract
[1,2-13C2]ABA, which is designed as a stable and pure internal standard for GC/MS analysis, is synthesized through the Witting reaction of 1-hydroxy-4-keto-α-ionone with carbomethoxymethylenetriphenylphosphorane prepared from [1,2-13C2]bromoacetic acid followed by saponification of the product methyl [1,2-13C2]ABA.
References
- J. A. D. Zeevaart and R. A. Creelman, Ann. Rev. Plant. Physiol. Plant. Mol. Biol., 1988, 39, 439 CrossRef CAS.
- B. V. Milborrow, Chem. Commun., 1969, 966 RSC.
- A. G. Netting, B. V. Milborrow and A. M. Duffield, Phytochemistry, 1982, 21, 385 CrossRef CAS.
- D. L. Roberts, R. A. Heckman, B. P. Hege and S. A. Bellin, J. Org. Chem., 1968, 33, 3566 CrossRef CAS.