Selective Synthesis of C2–C4 Olefins and C5+ Hydrocarbons over Unpromoted and Cerium-promoted Iron Catalysts Supported on Ion Exchanged (H, K) Zeolite-Y

(Note: The full text of this document is currently only available in the PDF Version )

Sang-Sung Nam, Gurram Kishan, Myung-Woo Lee, Myoung-Jae Choi and Kyu-Wan Lee


Abstract

Hydrogenation of CO2 to hydrocarbons is carried out on unpromoted and Ce-promoted iron catalysts supported on ion exchanged (H, K) zeolite-Y; the results suggest that the Fe–Ce/KY catalyst has significant advantages being highly selective for C2–C4 olefins and C5+ hydrocarbons.


References

  1. J. H. Edwards, Catal. Today, 1995, 23, 59 CrossRef CAS.
  2. M. D. Lee, J. F. Lee and C. S. Chang, Bull. Chem. Soc. Jpn., 1989, 62, 2756 CAS.
  3. J. F. Lee, W. S. Chern and M. D. Lee, Can. J. Chem. Eng., 1992, 70, 511 Search PubMed.
  4. P. H. Choi, K. W. Jun, S. J. Lee, M. J. Choi and K. W. Lee, Catal. Lett., 1996, 40, 115 CAS.
  5. J. Barrault, A. Guilleminot, J. C. Achard, V. Paul-Bancour and A. Percheron-Guegan, Appl. Catal., 1986, 21, 307 CrossRef CAS.
  6. K. Chen and Q. Yan, Appl. Catal. A, Gen., 1997, 158, 215 CrossRef CAS.
  7. A. Guerrero-Ruiz, A. Sepulveda-Escribano and I. Rodriguez-Ramos, Appl. Catal. A, Gen., 1994, 120, 71 CrossRef CAS.
  8. D. Z. Wang, X. P. Cheng, Z. E. Huang, X. Z. Wang and S. Y. Peng, Appl. Catal., 1991, 77, 109 CrossRef CAS.
  9. U.S. Pat., 3130009, 1970 Search PubMed.
  10. M. Pijolat, V. Perrichon, M. Premet and P. Bussiere, J. Mol. Catal., 1982, 17, 367 CrossRef CAS.
  11. H. P. Bonzel and H. J. Krebs, Surf. Sci., 1982, 117, 639 CrossRef CAS.
  12. T. H. Fleish, R. F. Hicks and A. T. Bell, J. Catal., 1984, 87, 398 CrossRef.
  13. N. Takahashi, T. Mori, A. Miyamoto, T. Hatori and Y. Murakami, Appl. Catal., 1988, 38, 61 CrossRef CAS.
  14. W. M. H. Sachtler, D. F. Shriver, W. B. Hollenberg and A. F. Lang, J. Catal., 1985, 92, 429 CrossRef CAS.
  15. P. Biloen and W. M. H. Sachtler, Adv. Catal., 1981, 30, 165 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.