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DOI: 10.1039/A900025I (Paper) Reference Section for: J. Chem. Res. (S), 1999, 268-269

A Practical and Efficient Procedure for Preparation of Diacetals from 2,2-Bis(hydroxymethyl)propane-1,3-diol with Aldehydes and Ketones Catalysed by Anhydrous Ferrous Sulfate

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Tong-Shou Jin, Yan-Ran Ma, Tong-Shuang Li and Jian-Xin Wang

Abstract

Synthesis of diacetals in excellent yields from aldehydes and ketones with 2,2-bis(hydroxymethyl)propane-1,3-diol is carried out in refluxing benzene or toluene with anhydrous ferrous sulfate as catalyst.

References

  1. Z.-H. Zhang, T.-S. Li, T.-S. Jin and J.-T. Li, J. Chem. Res. (S), 1998, 640 RSC.
  2. T. N. Shakhtakhtinskii and L. V. Andreev, Dokl. Akad. Nauk. Azerb. SSR, 1962, 18, 17 (Chem. Abstr., 1963, 59, 3762g) Search PubMed.
  3. J. Perner, K. Stork, F. Merger and K. Oppenlaender, Ger. Offen, 1978, 2707875 (Chem, Abstr., 1978, 89, 181503) Search PubMed.
  4. S. F. Marrian, Chem. Rev., 1948, 43, 149 CrossRef CAS.
  5. J. Read, J. Chem. Soc., 1912, 101, 2090 (Chem. Abstr., 1913, 7, 968) RSC.
  6. N. P. Klyushnik, Ukr. Khim. Zh., 1964, 30, 965 (Chem. Abstr., 1965, 62, 2717a) Search PubMed.
  7. D. Callejas, M. Echemique and H. Seeboth, Rev. Cubana Quim., 1988, 4, 73 (Chem. Abstr., 1989, 111, 77927a) Search PubMed.
  8. E. Bograchov, J. Am. Chem. Soc., 1950, 72, 2268 CrossRef CAS.
  9. V. G. Mkhitaryan, J. Gen. Chem., 1939, 9, 1923 (Chem. Abstr., 1940, 34, 4381) Search PubMed.
  10. H. J. Backer and H. B. Schurink, Rec. Trav. Chim., 1931, 50, 1066 (Chem. Abstr., 1932, 26, 964) CAS.
  11. L. Orthner, Ber., 1928, 61B, 116 Search PubMed.
  12. X. Chen, Y.-T. Xu and C.-X. Jin, Hecheng Huaxue, 1997, 5, 212 Search PubMed.
  13. T.-S. Jin, T.-S. Li, Z.-H. Zhang and Y.-J. Yuan, Synth. Commun., 1999, 29, in press Search PubMed.
  14. C.-D. Wang, X.-Z. Shi and R.-J. Xie, Synth. Commun., 1997, 27, 2517 CAS.
  15. T.-S. Jin, Y.-R. Ma, Z.-H. Zhang and T.-S. Li, Org. Prep. Proced. Int., 1998, 30, 463 CAS.
  16. T.-S. Jin, G.-Y. Du and T.-S. Li, Indian J. Chem., Sect. B, 37, 939 Search PubMed.
  17. T.-S. Li, Z.-H. Zhang, T.-S. Jin and Y.-L. Li, Chin. Chem. Lett., 1998, 9, in press Search PubMed.