Tin Chloride Catalysed Oxidation of Acetone with Hydrogen Peroxide to Tetrameric Acetone Peroxide

(Note: The full text of this document is currently only available in the PDF Version )

Heng Jiang, Gang Chu, Hong Gong and Qingdong Qiao


Abstract

SnCl4·5H2O and SnCl2·2H2O are efficient catalysts for the oxidation of acetone with 30% hydrogen peroxide at room temperature and produce tetrameric acetone peroxide which is identified by molecular weight determination, elemental analysis, FTIR, NMR and MS.


References

  1. R. A. Sheldon and J. K. Kochi, Metal-Catalyzed Oxidation of Organic Compounds, Academics Press, New York, 1981 Search PubMed.
  2. G. Strukul, Metal Catalysis in Hydrogen Peroxide Oxidations, Reidel, Dordrecht, The Netherlands, 1991 Search PubMed.
  3. P. Battioni, J. P. Renaud, J. F. Bartoli and K. Mansuy, J. Chem. Soc., Chem. Commun., 1986, 341 RSC.
  4. J. Muzart and N'Ait Ajjou, J. Mol. Catal., 1991, 66, 155 CrossRef CAS.
  5. H. H. R. Barton, P. E. Eaton and W. G. Liu, Tetrahedron Lett., 1991, 32, 6263 CrossRef.
  6. K. Paul, P. R. Story, P. Busch and J. R. Sanderson, J. Org. Chem., 1976, 41, 1283 CrossRef CAS.
  7. P. R. Story, B. Lee, C. E. Bishop, D. Denson and P. Bush, J. Org. Chem., 1970, 35, 3059 CAS.
  8. J. R. Sanderson, R. J. Wilterdink and A. G. Zeiler, Synthesis, 1976, 479 CrossRef CAS.
  9. A. V. Tobolsky and R. B. Mesrobian, Organic Peroxides, Their Chemistry, Decomposition, and Role in Polymerization, Interscience, New York, 1954, p. 48 Search PubMed.
  10. M. S. Kharasch and M. Gladstone, J. Chem. Educ., 1939, 16, 498.
  11. G. Rothenberg, H. Wiener and Y. Sasson, J. Mol. Catal. A: Chem., 1998, 136, 253 CrossRef CAS.
  12. Carbon-13 NMR, Sadtler Research Laboratories. Inc, 1978, 4610C Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.