A Stereoselective Synthetic Route to (Z)-1-Arylthio Vinylstannanes

Abstract

Acetylenic stannanes react with Cp₂Zr(H)Cl (Cp=η⁵-C₅H₅) to give organozirconium(IV) complexes, which are trapped with arylsulfenyl chloride to afford (Z)-l-arylthio vinylstannanes.

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