DOI: 10.1039/A808311H
(Paper)
Reference Section for: J. Chem. Res. (S), 1999, 146-147
Kinetic Isotope Effects in the Chromium(VI) Oxidation of Bicyclic Alcohols
(Note: The full text of this document is currently only available in the PDF Version )
J. Hodge Markgraf, Jordan S. Dubow, Jessica A. Charland and Elliott H. Sohn
Abstract
Pseudo first-order rate constants are determined for the oxidation of a series of secondary alcohols and their monodeutero analogues by ammonium chromate in aqueous acidic solution at several temperatures; the relative rates and activation parameters are consistent with a cyclic, symmetrical transition state.
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