Synthesis, Reactivity and Crystal Structure of a Novel Cluster [Co3(CO)93-C)C(O)OCH2]2

(Note: The full text of this document is currently only available in the PDF Version )

Ji Zhang, Xue-Nian Chen, Er-Run Ding, Yuan-Qi Yin and Jie Sun


Abstract

The higher-nuclearity cluster compound [Co3(CO)93-C)C(O)OCH2]21 has been isolated from the reaction of [Cl3CC(O)OCH2]2 and Co2(CO)8, and its metal exchange reaction with Na[M(CO)35-C5H4C(O)C6H4C(O)OMe}] (M=Mo or W) has been discussed together with its structure determination by single-crystal X-ray diffraction methods.


References

  1. H. Vahrenkamp, Comments Inorg. Chem., 1985, 4, 253 CAS.
  2. H. P. Wu, Y. Q. Yin, X. Y. Huang and K. B. Yu, J. Organomet. Chem., 1995, 489, 119.
  3. H. P. Wu, Y. Q. Yin and Q. C. Yang, Inorg. Chim. Acta, 1996, 245, 143 CrossRef.
  4. E. R. Ding, S. L. Wu, Y. Q. Yin and J. Sun, J. Chem. Res. (S), 1998, 246 RSC.
  5. E. R. Ding, Y. Q. Yin and J. Sun, J. Organomet. Chem., 1998, 559, 157 CrossRef.
  6. D. Seyferth, J. E. Hallgren and P. L. K. Hung, J. Organomet. Chem., 1973, 50, 265 CrossRef CAS.
  7. B. R. Penfold and B. H. Robinson, Acc. Chem. Res., 1973, 6, 73 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.