Synthesis of (η5-R1C5H4)(CO)2Mo(η2-S2R) via Reaction of (µ-RS)(µ-p-MeC6H4SO2S)Fe2(CO)6 with Nucleophiles (η5-R1C5H4)(CO)3MoSeNa. Crystal Structure of (η5-MeO2CC5H4)(CO)2Mo(η2-S2But)

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Li-Cheng Song, Qing-Mei Hu and Xiang-Dong Qin


Abstract

The reaction of (µ-RS)(µ-p-MeC6H4SO2S)Fe2(CO)6 with (η5-R1C5H4)(CO)3MoSeNa gave organomolybdenum complexes (η5-R1C5H4)(CO)2Mo(η2-S2R) (3a R=Et, R1=H; 3b R=But, R1=MeO2C), the structure of 3b being determined by X-ray diffraction analysis.


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