DOI: 10.1039/A806834H
(Paper)
Reference Section for: J. Chem. Res. (S), 1999, 82-83
Geometrical Preferences in Bis(dithiocarbamato)tin(IV) Complexes: X-Ray Structure of cis-I2Sn[S2CN(C2H5)2]2 and Theoretical Investigations
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Radhakrishnan Selvaraju, Mariappan Manoharan, Parthasarathi Laavanya, Krishnaswamy Panchanatheswaran and Ponnambalam Venuvanalingam
Abstract
The geometry of cis-I2Sn[S2CN(C2H5)2]2 is confirmed by single crystal X-ray analysis; the spectral data of the complex resemble those of the bromo complex and PM3 calculations on octahedral complexes of the type XYSn[S2CN(C2H5)2]2 reveal that their geometrical preferences depend upon the electron availability on the monodentate ligands X or Y.
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