DOI: 10.1039/A806474A
(Paper)
Reference Section for: J. Chem. Res. (S), 1999, 68-69
Synthesis of Triethyl N-Formyl-N-phosphonomethylglycinate and Diethyl N-Formyl-N-phosphonomethylglycine and Studies of Their Rotational Conformers by Dynamic NMR
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Zyta Ziora, Tomasz Cierpicki, Jolanta Grembecka and Paweł Kafarski
Abstract
Reaction of ethyl N-phosphonomethylglycinate with triethyl orthoformate gave a mixture of triethyl N-formyl-N-phosphonomthylglycinate (3) and diethyl N-formyl-N-phosphonomethylglycine (4), the rotational barriers of which have been investigated theoretically and experimentally.
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