Thermally Unstable 5-(9-Anthrylmethyl)-10-methyl-5,10-dihydrophenazine

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Akira Sugimoto, Keisuke Matsumoto, Hideyuki Maruyama, Kazuhiko Mizuno and Kaku Uehara


Abstract

The title compound in refluxing toluene decomposed to 9-anthrylmethyl derivatives and phenazine as major products upon cleavage of the N–CH2 bond; the orbital interaction of which with π-orbitals of the aromatic ring was suggested by the X-ray crystal structure analysis.


References

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