Remarkable Fast Microwave-assisted Zeolite HZSM-5 Catalyzed Oxidation of Alcohols with Chromium Trioxide under Solvent-free Conditions

(Note: The full text of this document is currently only available in the PDF Version )

Majid M. Heravi, Dariush Ajami, Kourosh Tabar-Hydar and Mitra Ghassemzadeh


Abstract

A variety of alcohols are oxidized to the corresponding carbonyl compounds in excellent yields by chromium trioxide–HZSM-5 zeolite under microwave irradiation in a solventless system.


References

  1. R. A. Abramovitch, Org. Prep. Proc. Int., 1991, 23, 685.
  2. R. Laurent, A. Laparterrie, J. D. J. Berlan, S. Lafeuvre and M. Audhuy, J. Org. Chem., 1992, 57, 7099 CrossRef CAS.
  3. A. Bose, M. Manhas, M. Ghosh, M. Shah, V. Rajur, S. Basi, S. Nowz, B. Banik, A. Chaudhary and K. Barakat, J. Org. Chem., 1992, 56, 6968.
  4. S. Caddick, Tetrahedron, 1995, 51, 10403 CrossRef.
  5. Solid Supports and Catalysts in Organic Chemistry, Ellis Horwood, London, 1992 Search PubMed.
  6. M. Onaka, A. Umezano, M. Kawai and Y. Izumi, J. Chem. Soc., Chem. Commun., 1985, 1202 RSC; M. E. Davis, Acc. Chem., 1993, 26, 111 CrossRef CAS; S. L. Suib, Chem. Rev., 1993, 93, 803 CrossRef CAS; T. Sano, T. Sekin, Z. Wang, K. Soga, I. Takahashi and T. Masuda, Chem. Commun., 1997, 1827 RSC.
  7. R. C. Larock, Comprehensive Organic Transformations, VCH, Weinheim, 1989 Search PubMed; M. Hudlicky, Oxidation in Organic Chemistry, ACS Manograph 86, American Chemical Society, Washington DC, 1990 Search PubMed; A. H. Hainis, Methods for Oxidation of Organic Compounds, Alcohols, Alcohol Derivatives, Alkyl Halides, Nitroalkanes, Alkylazides, Carbonyl Compounds, Hydroxy Arenes and Amino Arenes, Academic Press, London, 1988 Search PubMed.
  8. A. Mancuso, S. L. Huang and D. Swern, J. Org. Chem., 1978, 43, 2480 CrossRef CAS; M. Hirano, H. Kuroda and T. Marimoto, Bull. Chem. Soc. Jpn., 1990, 63, 2433 CAS; W. X. Lou and J. D. Lou, Synth. Commun., 1992, 767 CAS; S. Ait-Mohan, F. Henin and J. Muzart, Tetrahedron Lett., 1995, 36, 2473 CrossRef; A. D. de Oleverira, B. G. Mureira, P. J. S. Maran and J. A. R. Rodrigius, Tetrahedron Lett., 1996, 37, 35029.
  9. D. B. Dess and J. C. Martin, J. Org. Chem., 1983, 48, 4155 CrossRef CAS.
  10. S. V. Pitre, V. R. Reddy and Y. D. Vanker, J. Chem. Res. (S), 1997, 462 RSC.
  11. M. M. Heravi, H. A. Oskooie and M. Mafi, Synth. Commun., 1997, 27, 1725 CAS.
  12. M. M. Heravi, M. Tajbakhsh, Y. Sh. Beheshtiha and H. A. Oskooie, Indian J. Heterocycl. Chem., 1996, 6, 143 Search PubMed.
  13. M. M. Heravi, D. Ajami and M. Ghassemzadeh, Synth. Commun., 1999, in press Search PubMed.
  14. M. M. Heravi, M. Tajbakhsh, B. Mohajerani and M. Ghassemzadeh, Synth. Commun., in press Search PubMed.
  15. M. M. Heravi, K. Aghapoor, M. A. Nooshabadi and M. M. Mojtahedi, Monatsh. Chem., 1997, 128, 1143 CAS.
  16. K. Aghapoor, M. M. Heravi and M. A. Nooshabadi, Indian J. Chem., Sect. B, 1998, 37, 84.
  17. M. M. Heravi, D. Ajami, M. M. Mojtahedi and M. Ghassemzadeh, Tetrahedron Lett., 1999, 40, 561 CrossRef CAS.
  18. M. M. Heravi, D. Ajami and M. Ghassemzadeh, Synthesis, 1999, in press Search PubMed.
  19. M. M. Heravi, D. Ajami and K. Tabar-Hydar, J. Chem. Res. (S), 1998, 620 RSC.
  20. T. Sano, N. Yamashita, Y. Iwami, K. Takeda and Y. Kawakami, Zeolites, 1996, 16, 258 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.