DOI: 10.1039/A901381D
(Paper)
Reference Section for: Green Chem., 1999, 1, 153-156
Enzymatic synthesis and NMR studies . of acylated sucrose acetates
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Marian C. Steverink-de Zoete, Marcel F. M. Kneepkens, Pieter de Waard, Marjolein Woudenberg-van Oosterom, Ted M. Slaghek and Kees F. Gotlieb
Abstract
The lipase-catalyzed esterification of partially acetylated sucrose has been studied. It was shown that the chemical acetylation increased the reaction rate of the subsequent enzymatic acylation. Thus it was possible to perform the enzymatic acylation in the absence of solvents while underivatized sucrose did not react. From HMBC NMR spectroscopy, it was concluded that the main site of acylation was the 6-position of the fructose moiety.
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