A catalogue of urban hydrocarbons for the city of Leeds: atmospheric monitoring of volatile organic compounds by thermal desorption-gas chromatography

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Suzanne Hassoun, Michael J. Pilling and Keith D. Bartle


Abstract

A method has been developed for the speciation and quantitative determination of hydrocarbons in urban air in the city of Leeds. Hydrocarbons were pre-concentrated by adsorbent tube air sampling and analysed using thermal desorption and gas chromatography with flame ionization detection and structural confirmation by mass spectrometric detection. While automated volatile organic compound (VOC) analysers produced data for a maximum of about 30 compounds simultaneously, with the method described here, a total of 68 C6-C12 hydrocarbons were measured simultaneously in one analysis at parts per billion (ppb) levels. Several monitoring surveys were performed, one during the winter of 1993 and the other in the summer of 1994, at a number of sites to investigate the levels of VOCs identified in the urban air of Leeds.


References

  1. A. J. Haagen-Smit, Ind. Eng. Chem., 1952, 44, 1342 CrossRef CAS.
  2. M. Lippmann, Environ. Sci. Technol., 1991, 25, 1954 CAS.
  3. D. I. Tingey and G. E. Taylor, Jr, Effects of Gaseous Air Pollution in Agriculture and Horticulture, Butterworths, London, 1982, pp. 27–42 Search PubMed.
  4. Department of the Environment, Transport and the Regions, The Fourth Report of the Photochemical Oxidants Review Group, London, 1997 Search PubMed.
  5. Expert Panel on Air Quality Standards (EPAQS), Benzene, Department of the Environment, HMSO, London, 1994 Search PubMed.
  6. W. P. L. Carter, J. A. Pierce, L. Dougmin and I. L. Malkina, Atmos. Environ., 1995, 29, 2499 CrossRef CAS.
  7. R. G. Derwent, Environ. Pollution, 1990, 63, 299 CAS.
  8. First Report of the Quality of Urban Air Review Group (QUARG), Urban Air Quality in the United Kingdom, Department of the Environment, London, 1993 Search PubMed.
  9. Her Majesty's Government, This Common Inheritance: Britain's Environmental Strategy, HMSO, London, 1990 Search PubMed.
  10. J. Derwent, P. Dumitrean, J. Chandier, T. J. Davies, R. G. Derwent, G. J. Dollard, M. Delaney, B. M. R. Jones and P. D. Nason, Report No. AEA/CS/1 8358030/005, AEA Technology, Culham, Oxon., UK, 1994 Search PubMed.
  11. J. Murlis, Proc. Int. Conf. on VOCs in the Environment, 27–28 October, London 1993, pp. 85–98 Search PubMed.
  12. P. Ciccioli, A. Cecinato, E. Brancaleoni, M. Frattoni and A. Liberti, J. High Res. Chromatog., 1992, 15, 75 Search PubMed.
  13. R. M. Smith, Gas and Liquid Chromatography in Analytical Chemistry, Wiley, Chichester, UK, 1988 Search PubMed.
  14. R. H. Brown and C. J. Purnell, J. Chromatog., 1979, 178, 79 CrossRef CAS.
  15. C. M. White, J. Hackett, R. R. Anderson, S. Kail and P. S. Spock, J. High Res. Chromatog., 1992, 15, 105 Search PubMed.
  16. D. Estel, M. Mohnke, F. Biermans and H. Rotzsche, J. High Res. Chromatog., 1995, 18, 403 Search PubMed.
  17. E. Kivi-Etelatalo, O. Kostiainen and M. Kokko, J. Chromatogr. A, 1997, 787, 205 CrossRef.
  18. L. S. Ettre, Anal. Chem., 1964, 36, 31A.
  19. R. H. Partridge, Proc. Int. Conf. on VOCs in the Environment, 27–28 October, London, 1993, pp. 361–373 Search PubMed.
  20. R. G. Derwent, M. E. Jenkin and S. M. Saunders, Atmos. Environ., 1996, 30, 181 CrossRef CAS.
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