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DOI: 10.1039/A907767G (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 4535-4540

Sodium, calcium, aluminium, zinc and europium salts of p-phenylenebis(silanetriolate). Access to a new class of organosilicates

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Bruno Boury, Robert J. P. Corriu, Valérie Le Strat and Rosario Nuñez

Abstract

The crystalline sodium salt of p-phenylenebis(silanetriolate), (NaO)3SiC6H4Si(ONa)3·14H2O has been prepared in quantitative yield by reaction of the corresponding alkoxysilane with NaOH. Characterization of its structure indicates two different environments for the silicon atoms (X-ray and 13C, 29Si, 1H NMR) in the solid state. Drying of the salt by thermal treatment between 20 and 180 °C (TG analysis) led to a modification of the structure without loss of the organic group. Elimination of C6H6 occurs above 200 °C and formation of the sodium silicate Na2SiO3 can be identified above 400 °C (X-ray diffraction). Quantitative replacement of the sodium cation with Al3+, Zn2+, Ca2+ and Eu3+ has been achieved resulting in the formation of the corresponding silanetriolates (EDX and elemental analyses). X-Ray diffraction analysis suggests the presence of a lamellar structure on very small domains or a short range order.

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