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DOI: 10.1039/A907755C (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 4127-4130

A novel example of self-assembly in lanthanide chemistry: synthesis and molecular structure of [Na(EtOH)6][Y9(µ4-O)2(µ3-OH)8{µ-η2-MeC(O)CHC(O)OEt}8{η2-MeC(O)CHC(O)OEt}8][hair space]†

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Liliane G. Hubert-Pfalzgraf, Nathalie Miele-Pajot, Renée Papiernik and Jacqueline Vaissermann

Abstract

The reaction between yttrium nitrate pentahydrate and the sodium salt of allyl acetatoacetate afforded nonanuclear cluster anions [Y9(µ4-O)2(µ3-OH)8{MeC(O)CHC(O)Z}16]–, the functional group Z being the initial allyl one OCH2CH[double bond, length half m-dash]CH2 or an ethoxide depending on the experimental conditions.

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