Syntheses and structures of dinuclear rhodium(I) complexes and 1-D zigzag-chain rhodium(I) co-ordination polymers bridged by rod-like bidentate nitrogen ligands[hair space]

(Note: The full text of this document is currently only available in the PDF Version )

Masahiko Maekawa, Kunihisa Sugimoto, Takayoshi Kuroda-Sowa, Yusaku Suenaga and Megumu Munakata


Abstract

Novel dinuclear rhodium(I) complexes, [Rh2(2-bpbd)2(cod)2]X2 (X = BF4 1a, PF6 1b or ClO4 1c; cod = cycloocta-1,5-diene) and 1-D rhodium(I) co-ordination polymers with the linkage of square-planar rhodium(I) centers, {[Rh(4-bpbd)(cod)]X}n (X = BF4 2a, PF6 2b or ClO4 2c) and {[Rh(4-bpe)(cod)]X}n(X = BF43a, PF6 3b or ClO4 3c), were systematically synthesized using 1,4-bis(2-pyridyl)butadiyne (2-bpbd), 1,4-bis(4-pyridyl)butadiyne (4-bpbd) and trans-1,2-bis(4-pyridyl)ethylene (4-bpe). The structures of 1a, 2a, 2b and 3a were crystallographically characterized. In 1a each Rh atom is bridged by two N atoms of 2-bpbd to afford a unique dinuclear structure with an 18-membered Rh2N4C12 framework. In 2a, 2b and 3a, each Rh atom is bonded to two N atoms of 4-bpbd (2a and 2b) or 4-bpe (3a) and two C[double bond, length half m-dash]C bonds of cod in a square-planar geometry. The square-planar centers are in turn linked by 4-bpbd or 4-bpe ligands to form a 1-D zigzag-chain structure. The zigzag chains are located in parallel 9.6, 9.9 and 10.7 Å apart in 2a, 2b and 3a, respectively, and no effective intermolecular interactions were found.


References

  1. M. Munakata, L.-P. Wu and T. Kuroda-Sowa, Bull. Chem. Soc. Jpn., 1997, 70, 1727 CAS; Adv. Inorg. Chem., 1999, 46, 173 Search PubMed; S. Kitagawa and M. Munakata, Trends Inorg. Chem., 1993, 3 Search PubMed; S. Kitagawa and M. Kondo, Bull. Chem. Soc. Jpn., 1998, 71, 1739 Search PubMed; Supramolecular Chemistry, eds. V. Balzani and L. De Cola, Kluwer, Dordrecht, 1992 CAS; Transition Metals in Supramolecular Chemistry, eds. L. Fabbrizzi and A. Poggi, Kluwer, Dordrecht, 1994 CAS; F. Vögtle, Supramolecular Chemistry, Wiley, Chichester, 1993 CAS; R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins and J. Liu, Supramolecular Architecture, ed. T. Bein, American Chemical Society, Washington, DC, 1992, ch. 19, p. 256 CAS; Comprehensive Supramolecular Chemistry, ed. J.-M. Lehn, Pergamon, Oxford, 1995, vol. 9 CAS; E. C. Constable, Prog. Inorg. Chem., 1994, 2, 92 CAS; J.-M. Lehn, Perspectives in Coordination Chemistry, eds. A. F. Williams, C. Floriani and A. E. Merbach, VHCA, Basel, 1992 Search PubMed; Adv. Inorg. Chem., 1989, 34, 1 Search PubMed; J.-M. Lehn, Angew. Chem., Int. Ed. Engl., 1988, 27, 89; 1990, 29, 1304 Search PubMed; A. Müller, H. Reuter and S. Dillinger, Angew. Chem., Int. Ed. Engl., 1995, 34, 2328 Search PubMed; V. Balzani, Tetrahedron, 1992, 48, 10443 Search PubMed.
  2. K. Maruoka, N. Murase and H. Yamamoto, J. Org. Chem., 1993, 58, 2938 CrossRef CAS.
  3. C. Chen and K. S. Suslick, Coord. Chem. Rev., 1993, 128, 293 CrossRef CAS and references therein.
  4. (a) H. O. Stumpf, L. Ouahab, Y. Pei, D. Grandjean and O. Kahn, Science, 1993, 261, 447 CrossRef; (b) F. Lloret, G. D. Munno, M. Julve, J. Cano, R. Ruiz and A. Caneschi, Angew. Chem., Int. Ed., 1998, 37, 135 CrossRef CAS; (c) J. A. Real, E. Andres, M. C. Munoz, M. Julve, T. Granier, A. Bousseksou and F. Varret, Science, 1995, 268, 265 CrossRef CAS.
  5. (a) B. F. Hoskins and R. Robson, J. Am. Chem. Soc., 1990, 112, 1546 CrossRef CAS; (b) C. L. Bowes and G. A. Ogin, Adv. Mater., 1996, 13 CAS.
  6. (a) M. Kondo, T. Yoshitomi, K. Seki, H. Matsuzaka and S. Kitagawa, Angew. Chem., Int. Ed. Engl., 1997, 36, 1725 CrossRef CAS; (b) D. Venkataraman, G. F. Gardner, S. Lee and J. S. Moore, J. Am. Chem. Soc., 1995, 117, 11600 CrossRef CAS.
  7. K. Biradha, K. V. Domasevitch, B. Moulton, C. Seward and M. J. Zaworotko, Chem. Commun., 1999, 1327 RSC; M. Fujita, Y. J. Kwon, S. Washizu and K. Ogura, J. Am. Chem. Soc., 1994, 116, 1151 CrossRef CAS; S. D. Huang and R.-G. Xiong, Polyhedron, 1997, 16, 3929 CrossRef CAS; J. Li, H. Zeng, J. Chen, Q. Wang and X. Wu, Chem. Commun., 1997, 1213 RSC; P. Losier and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1996, 35, 2779 CrossRef CAS; J. Lu, T. Paliwala, S. C. Lim, C. Yu, T. Niu and A. J. Jacobson, Inorg. Chem., 1997, 36, 923 CrossRef CAS; Q. Wang, X. Wu, W. Zhang, T. Sheng, P. Lin and J. Li, Inorg. Chem., 1999, 38, 2223 CrossRef; O. M. Yaghi, H. Li and T. L. Groy, Inorg. Chem., 1997, 36, 4292 CrossRef CAS.
  8. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Chem. Soc., Chem. Commun., 1994, 2755 RSC; R. W. Gable, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1990, 1677 RSC; L. R. MacGillivray, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1994, 1325 RSC; F. Robinson and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1995, 2413 RSC; S. Subramanian and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1995, 34, 2127 CrossRef CAS; O. M. Yagi and G. Li, Angew. Chem., Int. Ed. Engl., 1995, 34, 207 CrossRef CAS; O. M. Yagi and H. Li, J. Am. Chem. Soc., 1995, 117, 10401; 1996, 118, 295 Search PubMed.
  9. (a) M. Li, Z. Xu, X. You, Z. Dong and G. Guo, Polyhedron, 1993, 12, 921 CrossRef CAS; (b) A. S. Batsanov, M. J. Begley, P. Hubberstey and J. Stroud, J. Chem. Soc., Dalton Trans., 1996, 1947 RSC; (c) A. J. Blake, S. J. Hill, P. Hubberstey and W.-S. Li, J. Chem. Soc., Dalton Trans., 1998, 909 RSC; (d) M. Andruh, H. W. Roesky, M. Noltemeyer and H.-G. Schmidt, Z. Naturforsch., Teil B, 1994, 49, 31 CAS; (e) R.-G. Xiong, Z. Yu, C.-M. Liu and X.-Z. You, Polyhedron, 1997, 15, 2667 CrossRef; (f) C. Chen, D. Xu, Y. Xu and C. Cheng, Acta Crystallogr., Sect. C, 1992, 48, 1231 CrossRef; (g) D.-L. Zhu, Y.-P. Yu, G.-C. Guo, H.-J. Zhuang, J.-S. Huang, Q. Liu, Z. Xu and X.-Z. You, Acta Crystallogr., Sect. C, 1996, 52, 1963 CrossRef; (h) J. T. Sampanthar and J. J. Vittal, J. Chem. Soc., Dalton Trans., 1999, 1993 RSC.
  10. (a) M.-X. Li, G.-Y. Xie, Y.-D. Gu, J. Chen and P.-J. Zheng, Polyhedron, 1995, 9, 1235 CrossRef CAS; (b) F. Kubel and J. Strahle, Z. Naturforsch., Teil B, 1982, 37, 272 Search PubMed; (c) J. Lu, C. Yu, T. Niu, T. Paliwala, G. Crisci, F. Somosa and A. Jacobson, Inorg. Chem., 1999, 37, 4637 CrossRef CAS; (d) R. W. Gable, B. F. Hoskins and G. Winter, Inorg. Chim. Acta, 1985, 96, 151 CrossRef CAS; (e) K.-B. Yu, S.-H. Gou, X.-Z. You and Z. Xu, Z. Naturforsch., Teil C, 1991, 47, 2653 Search PubMed; (f) B. F. Abraham, B. F. Hoskins and G. Winter, Aust. J. Chem., 1990, 43, 1759; (g) I. Lange, E. Wieland, P. G. Jones and A. Blaschette, J. Organomet. Chem., 1993, 458, 57 CrossRef.
  11. (a) P.-J. Prest and J. S. Moore, Acta Crystallogr., Sect. C, 1996, 52, 2176 CrossRef; (b) J. Lu, G. Crisci, T. Niu and A. J. Jacobson, Inorg. Chem., 1997, 36, 5140 CrossRef CAS; (c) P. M. Slangen, P. J. V. Koningsbruggen, J. G. Haasnoot, J. Jansen, S. Gorter, J. Reedijk, H. Kooijman, W. J. J. Smeets and A. L. Spek, Inorg. Chim. Acta, 1993, 212, 289 CrossRef CAS.
  12. P. R. Sharp, Comprehensive Organometallic Chemistry II, eds. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1992, vol. 8, ch. 2, pp. 115–302 Search PubMed; C. E. Barnes, Comprehensive Organometallic Chemistry II, eds. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1992, vol. 8, ch. 4, pp. 419–520 Search PubMed; F. H. Jardine and P. S. Sheridan, Comprehensive Coordination Chemistry, eds. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, 1987, vol. 4, ch. 48, pp. 901–1098 Search PubMed; C. White, Dictionary of Organometallic Compounds, Second Edition, Chapman & Hall, London, 1995, vol. 3, pp. 3195–3397 Search PubMed.
  13. U. Fritzsche and S. Hunig, Tetrahedron Lett., 1972, 4831 CrossRef CAS; J. G. Rodriguez, R. Martin-Villamil, F. H. Cano and I. Fonseca, J. Chem. Soc., Perkin Trans. 1, 1997, 709 RSC.
  14. L. D. Ciana and A. Haim, J. Heterocycl. Chem., 1984, 21, 607 Search PubMed.
  15. T. G. Schenck, J. M. Downes, C. R. C. Milne, P. B. Mackenzie, H. Boucher, J. Whelan and B. Bosnich, Inorg. Chem., 1985, 24, 2334 CrossRef CAS.
  16. (a) SAPI 91, F. Hai-Fu, Structure Analysis Programs with Intelligent Control, Rigaku Corporation, Tokyo, 1991; (b) SIR 92, A. Altomare, M. C. Burla, M. Camalli, G. Cascarano, C. Giacovazzo and G. Polidori, J. Appl. Crystallogr., 1994, 27, 435 Search PubMed; (c) SIR 88, M. C. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, G. Polidori, R. Spagna and D. Viterbo, J. Appl. Crystallogr., 1989, 22, 389 Search PubMed.
  17. DIRDIF 94, P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel and J. M. M. Smits, The DIRDIF 94 program system, Technical report of the crystallography laboratory, University of Nijmegen, 1994.
  18. SHELXL 97, G. M. Sheldrick, program for the renement of crystal structures, University of Göttingen, 1997.
  19. D. T. Cromer and J. T. Waber, International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, 1974, vol. IV Search PubMed.
  20. TEXSAN, Crystal Structure Analysis Package, Molecular Structure Corporation, Houston, TX, 1985 and 1992.
  21. C. K. Johnson, ORTEP II, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
  22. C. Richardson and P. J. Steel, Inorg. Chem. Commun., 1998, 1, 260 CrossRef CAS.
  23. R. Uson, L. A. Oro, J. Gimeno, M. A. Ciriano, J. A. Cabeza, A. Tiripicchio and M. T. Camellini, J. Chem. Soc., Dalton Trans, 1983, 323 RSC; L. A. Oro, M. Esteban, R. M. Claramunt, J. Elguero, C. Foces-Foces and F. H. Cano, J. Organomet. Chem., 1984, 276, 79 CrossRef CAS; J. F. Robertson, A. Kadziola, R. A. Krause and S. Larsen, Inorg. Chem., 1989, 28, 2097 CrossRef CAS; M. Cocivera, G. Ferguson, B. Kaitner, F. J. Lalor, D. J. O'Sullivan, M. Parvez and B. Ruhl, Organometallics, 1982, 1, 1132 CrossRef CAS; K. Beveridge, G. W. Bushnell, S. R. Stobart, J. L. Atwood and M. J. Zaworotko, Organometallics, 1983, 2, 1447 CrossRef CAS; B. M. Louie, S. J. Retting, A. Storr and J. Trotter, Can. J. Chem., 1984, 62, 1057 CAS; A. Tiripicchio, M. T. Camellini, R. Uson, L. A. Oro, M. A. Ciriano and F. Viguri, J. Chem. Soc., Dalton Trans., 1984, 125 RSC.
  24. K. Swaminathan and U. C. Sinha, Acta Crystallogr., Sect. C, 1989, 45, 504 CrossRef.
  25. J. T. Lin, S.-S. Sun, J. J. Wu, L. Lee, K.-J. Lin and Y. F. Huang, Inorg. Chem., 1995, 34, 2323 CrossRef CAS.
  26. A. J. Blake, N. R. Champness, A. Khlobystov, D. A. Lemenovskii, W.-S. Li and M. Schröder, Chem. Commun., 1997, 2027 RSC.
  27. B. F. Abrahams, M. J. Hardie, B. F. Hoskins, R. Robson and E. E. Sutherland, J. Chem. Soc., Chem. Commun., 1994, 1049 RSC.
  28. J. R. Allan, M. J. Barrow, P. C. Beaumont, L. A. Macindoe, G. H. W. Milburn and A. R. Werninck, Inorg. Chim. Acta, 1988, 148, 85 CrossRef CAS.
  29. (a) M. J. Irwin, J. J. Vittal, G. P. A. Yap and R. J. Puddephatt, J. Am. Chem. Soc., 1996, 118, 13101 CrossRef CAS; (b) G. Mago, M. Hinago, H. Miyasaka, N. Matsumoto and H. Okawa, Inorg. Chim. Acta, 1997, 254, 145 CrossRef CAS; (c) Y.-B. Dong, R. C. Layland, M. D. Smith, N. G. Pschirer, U. H. F. Bunz and H.-C. zur Loye, Inorg. Chem., 1999, 38, 3056 CrossRef CAS; (d) D. Hagrman, R. P. Hammond, R. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 2091 CrossRef CAS.
  30. G. D. Munno, D. Armentano, T. Poerio, M. Julve and J. A. Real, J. Chem. Soc., Dalton Trans., 1999, 1813 RSC.
  31. A. J. Blake, N. R. Champness, S. S. M. Chung, W.-S. Li and M. Schröder, Chem. Commun., 1997, 1005 RSC.
  32. G. J. Ashwell, D. A. Kennedy and I. W. Nowell, Acta Crystallogr., Sect. C, 1983, 39, 733 CrossRef.
Click here to see how this site uses Cookies. View our privacy policy here.