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DOI: 10.1039/A905996B (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 3913-3917

Synthesis and complexation of tetrathiafulvalene derivatives functionalised with [15]aneS5 thioether crowns[hair space]†

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Neil Robertson, Sascha Vukojevic, Xiaoming Liu, Lesley J. Yellowlees and Simon Parsons

Abstract

Two new tetrathiafulvalene (TTF)-based molecules functionalised with [15]aneS5 groups have been prepared by phosphite mediated coupling reactions. The [15]aneS5–thione precursor has been characterised by X-ray crystallography. Cyclic voltammetry, spectroelectrochemistry and EPR studies of one of these TTF compounds with and without guest copper(II) ions have revealed binding of CuII and temperature dependent intramolecular electron transfer to give CuI and TTF+.

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