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DOI: 10.1039/A905911C (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 3735-3740

Control of the hapticity of pyridine-2-thiolate ligands in rhenium(V) oxo complexes[hair space]†

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António Paulo, Ângela Domingos and Isabel Santos

Abstract

Treatment of [ReO{κ3-B(pz)4}(OMe)2] 1 with pyridine-2-thiol ligands led to [ReO{κ2-B(pz)4}(κ2-Spy*)(OMe)] (Spy* = 2-SC5H4N 2 or 2-SC5H3NSiMe3-3 3) or [ReO{κ3-B(pz)4}(κ1-2-SC5H4N)2] 4, depending on the reaction conditions. Complexes 2 and 3 reacted with trimethylsilyl chloride yielding [ReO{κ3-B(pz)4}(κ1-2-SC5H4N)Cl]·HCl 6 and [ReO{κ3-B(pz)4}Cl2], respectively. The characterization of the new compounds involves IR and 1H NMR spectroscopies, and X-ray diffraction analysis for 3, 4 and 6.

References

  1. H. Spies, T. Fietz, H. J. Pietzsch, B. Johanssen, P. Leibnitz, G. Reck, D. Scheller and K. Klostermann, J. Chem. Soc., Dalton Trans., 1995, 2277 RSC.
  2. M. Papadopoulos, C. Tsoukala, I. Pirmettis, B. Nock, T. Maina, Z. Abedin, C. P. Raptopoulou, A. Terzis and E. Chiotellis, Inorg. Chim. Acta, 1999, 285, 97 CrossRef CAS.
  3. K. P. Maresca, G. H. Bonavia, J. W. Babich and J. Zubieta, Inorg. Chim. Acta, 1999, 284, 252 CrossRef CAS.
  4. D. J. Rose, K. P. Maresca, T. Nicholson, A. Davison, A. G. Jones, J. Babich, A. Fischman, W. Graham, J. R. D. DeBord and J. Zubieta, Inorg. Chem., 1998, 37, 2701 CrossRef CAS.
  5. D. J. Rose, K. P. Maresca, P. B. Kettler, Y. D. Chang, V. Soghomomian, Q. Chen, M. J. Abrams, S. K. Larsen and J. Zubieta, Inorg. Chem., 1996, 35, 3548 CrossRef CAS.
  6. P. B. Kettler, Y. Chang, D. Rose, J. Zubieta and M. J. Abrams, Inorg. Chim. Acta, 1996, 244, 199 CrossRef CAS.
  7. A. Domingos, J. Marçalo, A. Paulo, A. Pires de Matos and I. Santos, Inorg. Chem., 1993, 32, 5114 CrossRef CAS.
  8. A. Paulo, A. Domingos, A. Pires de Matos, I. Santos, M. F. N. N. Carvalho and A. J. L. Pombeiro, Inorg. Chem., 1994, 33, 4729 CrossRef CAS.
  9. A. Paulo, A. Domingos, J. Marçalo, A. Pires de Matos and I. Santos, Inorg. Chem., 1995, 34, 2113 CrossRef CAS.
  10. A. Paulo, A. Domingos and I. Santos, Inorg. Chem., 1996, 35, 1798 CrossRef CAS.
  11. D. Nunes, A. Domingos, L. Patrício, A. Paulo, I. Santos, M. F. N. N. Carvalho and A. J. L. Pombeiro, Inorg. Chim. Acta, 1998, 271, 65 CrossRef CAS.
  12. A. Paulo, A. Domingos and I. Santos, Inorg. Chem., 1998, 37, 6807 CrossRef CAS.
  13. E. Block, M. Gernon, H. Kang, G. Ofori-Okai and J. Zubieta, Inorg. Chem., 1991, 30, 1736 CrossRef CAS.
  14. C. K. Fair, MOLEN, Enraf-Nonius, Delft, 1990.
  15. G. M. Sheldrick, SHELXS 86, Program for the Solution of Crystal Structure, University of Göttingen, 1986.
  16. G. M. Sheldrick, SHELXS 93, Program for the Renement of Crystal Structure, University of Göttingen, 1993.
  17. C. K. Johnson, ORTEP II, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976; P. McArdle, J. Appl. Crystallogr., 1995, 28, 65 Search PubMed.
  18. N. S. Gobulev, I. G. Shendervich, S. N. Smirnov, G. S. Denisov and H. H. Limbach, Chem. Eur. J., 1999, 5, 492 CrossRef.
  19. A. Paulo, J. Ascenso, A. Domingos, A. Galvão and I. Santos, J. Chem. Soc., Dalton Trans., 1999, 1798 Search PubMed.
  20. G. F. Ciani, G. D'Alfonso, P. F. Romiti, A. Sironi and M. Freni, Inorg. Chim. Acta, 1983, 72, 29 CrossRef CAS.
  21. S. Abram, U. Abram, E. Schulz-Lang and J. Strahle, Acta Crystallogr., Sect. C, 1995, 51, 1078 CrossRef.
  22. I. A. Degnan, J. Behm, M. R. Cook and W. A. Herrmann, Inorg. Chem., 1998, 37, 6807 CrossRef CAS.
  23. P. B. Kettler, Y. D. Chang, Q. Chen, J. Zubieta, M. J. Abrams and S. K. Larsen, Inorg. Chim. Acta, 1995, 231, 13 CrossRef CAS.
  24. L. C. Damude, P. A. W. Dean, V. Manivannan, R. S. Srivastava and J. J. Vitall, Can. J. Chem., 1990, 68, 1323 CAS.
  25. S. M. Redmore, C. E. F. Rickard, S. J. Webb and L. J. Wright, Inorg. Chem., 1997, 36, 4743 CrossRef CAS.
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