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DOI: 10.1039/A905574F (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1999, 3329-3330

Facile formation of a titanium–carbon bond from TiCl4 by HCl elimination: the synthesis and structure of TiCl3[Me3SiNP(Ph)2CHCH2P(Ph)2NSiMe3][hair space]†

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Mark J. Sarsfield, Mark Thornton-Pett and Manfred Bochmann

Abstract

The reaction of TiCl4 with the bis-phosphinimine Me3SiN[double bond, length half m-dash] P(Ph)2CH2CH2P(Ph)2[double bond, length half m-dash]NSiMe3 1 proceeds with evolution of HCl and metallation of one CH2 group to give TiCl3{Me3SiNP(Ph)2CHCH2P(Ph)2NSiMe3} 2. The crystal structure of 2 is solved and shows a comparatively long Ti–C bond.

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