Synthesis, structural characterization and catalytic properties of a novel monomeric rhenium(V)methyl(oxo)bis(η2-picolinato) complex: [CH3Re(O)(pic)2][hair space]

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Alexis Deloffre, Sabine Halut, Laurent Salles, Jean-Marie Brégeault, José Ribeiro Gregorio, Bernard Denise and Henri Rudler


Abstract

A methyl mono-oxo rhenium(V) complex with two picolinato chelating ligands has been synthesized and structurally characterized. When reacted with excess 10 or 30% H2O2 it forms peroxo species responsible for the catalytic activity of a highly selective two-phase medium.


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