New approach to dichloroindium amides

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Jörg Prust, Peter Müller, Carsten Rennekamp, Herbert W. Roesky and Isabel Usón


Abstract

Two different routes are presented for the synthesis of dichloroindium amides. On the one hand we prepared (THF)3Li(µ-Cl)Cl2InN(SiMe3)(Dipp) (1) (Dipp = 2,6-diisopropylphenyl) by the reaction of indium trichloride with the lithiated aniline, on the other hand Cl2InNEt2 (2) by trimethylsilyl chloride elimination. Compound 1 was characterized by X-ray strucural analysis.


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