A three-dimensional organic–inorganic composite material constructed from copper–triazolate networks linked through vanadium oxide chains: [{Cu3(trz)2}V4O12]

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Pamela J. Hagrman, Craig Bridges, John E. Greedan and Jon Zubieta


Abstract

The hydrothermal reaction of a mixture of V2O5, 1,2,4-triazole (trz), Cu(NO3)2·2.5H2O and H2O yields [{Cu3(trz)2}V4O12], a material constructed from one-dimensional {V4O12}n4n chains linked to undulating {Cu3(trz)2}n4n+ networks.


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